Influence of temperature and sliding speed on the subsurface microstructure evolution of EN AW-6060 under sticking friction conditions

This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. This article appeared in AIP Conference Proceedings 1896, 140012 (2017) and may be found at https://doi.org/10.1063/1.5008168.The microstructure evolution of the friction boundary layer of the aluminum alloy EN AW-6060 was investigated. Sticking friction tests at different temperatures and sliding speeds were carried out. A severe deformation below the friction surface was observed by means of LOM and EBSD mapping. Thus, the thickness variation and the grain structure of the high deformation zone could be described. Fibrous structure was observed at 300 °C and 400 °C, while equiaxed grains with high misorientation angle (>15°) were generated at higher temperatures. Additionally, abnormal grain growth and coarse grains were detected at high sliding speeds (10 mm/s, 42 mm/s) at 450°C and 500 °C respectively

Modeling Mental Qualities

Conscious experiences are characterized by mental qualities, such as those involved in seeing red, feeling pain, or smelling cinnamon. The standard framework for modeling mental qualities represents them via points in geometrical spaces, where distances between points inversely correspond to degrees of phenomenal similarity. This paper argues that the standard framework is structurally inadequate and develops a new framework that is more powerful and flexible. The core problem for the standard framework is that it cannot capture precision structure: for example, consider the phenomenal contrast between seeing an object as crimson in foveal vision versus merely as red in peripheral vision. The solution I favor is to model mental qualities using regions, rather than points. I explain how this seemingly simple formal innovation not only provides a natural way of modeling precision, but also yields a variety of further theoretical fruits: it enables us to formulate novel hypotheses about the space and structures of mental qualities, formally differentiate two dimensions of phenomenal similarity, generate a quantitative model of the phenomenal sorites, and define a measure of discriminatory grain. A noteworthy consequence is that the structure of the mental qualities of conscious experiences is fundamentally different from the structure of the perceptible qualities of external objects

Metallic salt deposition on porous particles by dry impregnation in fluidized bed: Effect of drying conditions on metallic nanoparticles distribution

In this paper, the fluidized bed dry impregnation of coarse alumina porous particles by a metallic salt, manganese nitrate, is investigated. In this technique the penetration of each drop of metallic solution in the porous solid particle and solvent evaporation takes place at the same time, then liquid diffusion phenomenon is negligible. So, the metal loading is directly related to the operating time and liquid flow rate and concentration. It is found that the competition between two phenomena, drying and capillary flow, controls the deposit location. In order to determine the importance of the solvent evaporation process compared to the solution penetration by capillarity, an impregnation module, IM, was defined as the ratio between the drying characteristic time and a capillary penetration time. The adequate choice of the operating conditions (bed temperature, liquid and fluidization gas flow rate) allows a uniform deposition of the metallic precursor inside the porous matrix or on the support surface. The impregnation under slow drying conditions (IM ≥ 10 and solvent content in the bed atmosphere τs ≥ 0.2) leads to a homogeneous deposition inside the pores. Under fast drying conditions (IM < 5 and τs < 0.2), the deposit is located at the particle external surface.In the case of slow drying, the impregnation kinetics can be represented by a “shrinking core” model. The critical impregnation rate is controlled by the competition between dissolution and recrystallization at the elementary grain scale. The size of the metal crystallites depends on the pore mean size and size distribution and on the drying rate

Technological novelty profile and invention's future impact

We consider inventions as novel combinations of existing technological capabilities. Patent data allow us to explicitly identify such combinatorial processes in invention activities. Unconsidered in the previous research, not every new combination is novel to the same extent. Some combinations are naturally anticipated based on patent activities in the past or mere random choices, and some appear to deviate exceptionally from existing invention pathways. We calculate a relative likelihood that each pair of classification codes is put together at random, and a deviation from the empirical observation so as to assess the overall novelty (or conventionality) that the patent brings forth at each year. An invention is considered as unconventional if a pair of codes therein is unlikely to be used together given the statistics in the past. Temporal evolution of the distribution indicates that the patenting activities become more conventional with occasional cross-over combinations. Our analyses show that patents introducing novelty on top of the conventional units would receive higher citations, and hence have higher impact.Comment: 20 pages, 7 figure

Focus ion beam/scanning electron microscopy characterization of osteoclastic resorption of calcium phosphate substrates

This article presents the application of dual focused ion beam/scanning electron microscopy (FIB-SEM) imaging for preclinical testing of calcium phosphates with osteoclast precursor cells and how this high-resolution imaging technique is able to reveal microstructural changes at a level of detail previously not possible. Calcium phosphate substrates, having similar compositions but different microstructures, were produced using low- and high-temperature processes (biomimetic calcium-deficient hydroxyapatite [CDHA] and stoichiometric sintered hydroxyapatite, respectively). Human osteoclast precursor cells were cultured for 21 days before evaluating their resorptive potential on varying microstructural features. Alternative to classical morphological evaluation of osteoclasts (OC), FIB-SEM was used to observe the subjacent microstructure by transversally sectioning cells and observing both the cells and the substrates. Resorption pits, indicating OC activity, were visible on the smoother surface of high-temperature sintered hydroxyapatite. FIB-SEM analysis revealed signs of acidic degradation on the grain surface under the cells, as well as intergranular dissolution. No resorption pits were evident on the surface of the rough CDHA substrates. However, whereas no degradation was detected by FIB sections in the material underlying some of the cells, early stages of OC-mediated acidic degradation were observed under cells with more spread morphology. Collectively, these results highlight the potential of FIB to evaluate the resorptive activity of OC, even in rough, irregular, or coarse surfaces where degradation pits are otherwise difficult to visualize.Peer ReviewedPostprint (author's final draft

The Chameleon Architecture for Streaming DSP Applications

We focus on architectures for streaming DSP applications such as wireless baseband processing and image processing. We aim at a single generic architecture that is capable of dealing with different DSP applications. This architecture has to be energy efficient and fault tolerant. We introduce a heterogeneous tiled architecture and present the details of a domain-specific reconfigurable tile processor called Montium. This reconfigurable processor has a small footprint (1.8 mm$^2$ in a 130 nm process), is power efficient and exploits the locality of reference principle. Reconfiguring the device is very fast, for example, loading the coefficients for a 200 tap FIR filter is done within 80 clock cycles. The tiles on the tiled architecture are connected to a Network-on-Chip (NoC) via a network interface (NI). Two NoCs have been developed: a packet-switched and a circuit-switched version. Both provide two types of services: guaranteed throughput (GT) and best effort (BE). For both NoCs estimates of power consumption are presented. The NI synchronizes data transfers, configures and starts/stops the tile processor. For dynamically mapping applications onto the tiled architecture, we introduce a run-time mapping tool

A reconnaissance geochemical drainage survey of the Criffel-Dalbeattie granodiorite complex and its environs

Regional geochemical reconnaissance by stream sediments and panned concentrates was undertaken over an area of 850 km 2 of south-west Scotland. Rocks of Ordovician to Permian age are exposed within the area but the major part is occupied by the Criffel-Dalbeattie granodiorite complex. Multi-element analysis of the samples collected demonstrates patterns of trace element distribution related to the geology and Broad-scale patterns in the distribution of some elements reflect compositional anumber of mineralisation. variations in both the Lower Palaeozoic turbidite sequence and the Criffel- Dalbeattie granodiorite complex, both of which may be sub-divided into specific units on the basis of the geochemical data. The follow-up of copper anomalies in drainage samples from the Black Stockarton Moor area led to the discovery of porphyry-style copper mineralisation within an arcuate belt at least 5 km by 1 km within the Black Stockarton Moor subvolcanic complex and of related disseminated copper mineralisation at Screel Burn. The area to the west of the Criffel-Dalbeattie plutonic complex is also characterised by relatively high boron levels in stream sediments reflecting the widespread occurrence of tourmaline both in association with and peripheral to the copper mineralisation. Vein mineralisation, usually containing baryte in addition to base.metals, is also identifiable from the drainage survey at the eastern margin of the Criffel-Dalbeattie granodiorite; in association with the Lower Carboniferous rocks along the Solway coast; and within the Lower Palaeozoic turbidites in the west of the area

Mechanical property evaluation of an Al-2024 alloy subjected to HPT processing

An aluminum-copper alloy (Al-2024) was successfully subjected to high-pressure torsion (HPT) up to five turns at room temperature under an applied pressure of 6.0 GPa. The Al-2024 alloy is used as a fuselage structural material in the aerospace sector. Mechanical properties of the HPT-processed Al-2024 alloy were evaluated using the automated ball indentation technique. This test is based on multiple cycles of loading and unloading where a spherical indenter is used. After two and five turns of HPT, the Al-2024 alloy exhibited a UTS value of ~1014 MPa and ~1160 MPa respectively, at the edge of the samples. The microhardness was measured from edges to centers for all HPT samples. These results clearly demonstrate that processing by HPT gives a very significant increase in tensile properties and the microhardness values increase symmetrically from the centers to the edges. Following HPT, TEM examination of the five-turn HPT sample revealed the formation of high-angle grain boundaries and a large dislocation density with a reduced average grain size of ~80 nm. These results also demonstrate that high-pressure torsion is a processing tool for developing nanostructures in the Al-2024 alloy with enhanced mechanical propertie